| 1991 | 1 | | 19 | FrRnd | 19 | Rangers | Benji Gil (minors) | 3.0 | 604 | 1610 | 32 | .237 | .641 | | | | | | | HS | Castle Park HS (Chula Vista, CA) |
| 1991 | 1 | | 20 | FrRnd | 20 | Reds | Pokey Reese (minors) | 6.3 | 856 | 2833 | 44 | .248 | .659 | | | | | | | HS | Lower Richland HS (Hopkins, SC) |
| 1991 | 1 | | 26 | FrRnd | 26 | Athletics | Brent Gates (minors) | 5.6 | 685 | 2329 | 25 | .264 | .685 | | | | | | | 4Yr | University of Minnesota (Minneapolis, MN) |
| 1991 | 1s | | 29 | FrRnd | 29 | Astros | *Shawn Livesey (minors) | | | | | | | | | | | | | HS | Simeon HS (Chicago, IL) |
| 1991 | 1s | | 42 | FrRnd | 42 | Blue Jays | *Dante Powell (minors) | -0.2 | 70 | 74 | 2 | .270 | .755 | | | | | | | HS | Millikan HS (Long Beach, CA) |
| 1991 | 2 | | 54 | FrRnd | 10 | Phillies | Kevin Stocker (minors) | 5.9 | 846 | 2773 | 23 | .254 | .682 | | | | | | | 4Yr | University of Washington (Seattle, WA) |
| 1991 | 3 | | 77 | FrRnd | 4 | Twins | Keith Legree (minors) | | | | | | | | | | | | | HS | Statesboro HS (Statesboro, GA) |
| 1991 | 3 | | 91 | FrRnd | 18 | Dodgers | Todd Larocca (minors) | | | | | | | | | | | | | HS | Lovett School (Atlanta, GA) |
| 1991 | 3 | | 92 | FrRnd | 19 | Rangers | Larry Hanlon (minors) | | | | | | | | | | | | | 4Yr | University of Texas at Arlington (Arlington, TX) |
| 1991 | 3 | | 94 | FrRnd | 21 | Blue Jays | Chris Stynes (minors) | 8.2 | 828 | 2326 | 51 | .275 | .734 | | | | | | | HS | Boca Raton Community HS (Boca Raton, FL) |
| 1991 | 4 | | 106 | FrRnd | 7 | Royals | Dwayne Gerald (minors) | | | | | | | | | | | | | HS | St. Paul's HS (St. Paul's, NC) |
| 1991 | 4 | | 110 | FrRnd | 11 | Mariners | Desi Relaford (minors) | -0.5 | 939 | 2939 | 40 | .243 | .666 | 1 | 0 | 0 | 0.00 | 0.00 | 0 | HS | Sandalwood HS (Jacksonville, FL) |
| 1991 | 5 | | 130 | FrRnd | 5 | Brewers | Nomar Garciaparra (minors) | 44.2 | 1434 | 5586 | 229 | .313 | .882 | | | | | | | HS | St. John Bosco HS (Bellflower, CA) |
| 1991 | 5 | | 132 | FrRnd | 7 | Royals | Shane Halter (minors) | 6.5 | 690 | 1899 | 45 | .246 | .688 | 2 | 0 | 0 | 0.00 | 2.00 | 0 | 4Yr | University of Texas at Austin (Austin, TX) |
| 1991 | 5 | | 135 | FrRnd | 10 | Phillies | Steve Verdusco (minors) | | | | | | | | | | | | | HS | Bellarmine College Preparatory (San Jose, CA) |
| 1991 | 6 | | 152 | FrRnd | 1 | Yankees | Eric Knowles (minors) | | | | | | | | | | | | | HS | St. Brendan HS (Miami, FL) |
| 1991 | 7 | | 184 | FrRnd | 7 | Royals | Paul Failla (minors) | | | | | | | | | | | | | HS | North Allegheny HS (Wexford, PA) |
| 1991 | 7 | | 185 | FrRnd | 8 | Padres | Homer Bush (minors) | 3.0 | 409 | 1274 | 11 | .285 | .682 | | | | | | | HS | East St. Louis HS (East St. Louis, IL) |
| 1991 | 7 | | 201 | FrRnd | 24 | Pirates | Tony Womack (minors) | 2.2 | 1303 | 4963 | 36 | .273 | .673 | | | | | | | 4Yr | Guilford College (Greensboro, NC) |
| 1991 | 8 | | 211 | FrRnd | 8 | Padres | Manny Cora (minors) | | | | | | | | | | | | | HS | Pedro Albizu Campos HS (Levittown, PR) |
| 1991 | 8 | | 213 | FrRnd | 10 | Phillies | David Hayden (minors) | | | | | | | | | | | | | 4Yr | University of Tennessee (Knoxville, TN) |
| 1991 | 8 | | 220 | FrRnd | 17 | Angels | Kurt Ehmann (minors) | | | | | | | | | | | | | 4Yr | Arizona State University (Tempe, AZ) |
| 1991 | 8 | | 228 | FrRnd | 25 | White Sox | Demond Thomas (minors) | | | | | | | | | | | | | HS | Elizabethtown HS (Elizabethtown, KY) |
| 1991 | 8 | | 229 | FrRnd | 26 | Athletics | Scott Sheldon (minors) | -0.4 | 141 | 285 | 8 | .235 | .650 | 1 | 0 | 0 | 0.00 | 0.00 | 0 | 4Yr | University of Houston (Houston, TX) |
| 1991 | 9 | | 242 | FrRnd | 13 | Indians | Paul Meade (minors) | | | | | | | | | | | | | 4Yr | Oral Roberts University (Tulsa, OK) |
| 1991 | 9 | | 247 | FrRnd | 18 | Dodgers | Dennis Winicki (minors) | | | | | | | | | | | | | HS | Mona Shores HS (Muskegon, MI) |
| 1991 | 10 | | 256 | FrRnd | 1 | Yankees | Mike Muncy (minors) | | | | | | | | | | | | | HS | Adolfo Camarillo HS (Camarillo, CA) |
| 1991 | 10 | | 272 | FrRnd | 17 | Angels | Gary Hagy (minors) | | | | | | | | | | | | | 4Yr | University of California, Los Angeles (Los Angeles, CA) |
| 1991 | 10 | | 278 | FrRnd | 23 | Red Sox | Tony Rodriguez (minors) | 0.3 | 27 | 67 | 1 | .239 | .590 | | | | | | | 4Yr | College of Charleston (Charleston, SC) |
| 1991 | 10 | | 279 | FrRnd | 24 | Pirates | Chance Sanford (minors) | -0.7 | 19 | 36 | 0 | .167 | .439 | | | | | | | JC | San Jacinto College (Pasadena, TX) |
| 1991 | 11 | | 295 | FrRnd | 14 | Expos | Mark Grudzielanek (minors) | 26.4 | 1802 | 7052 | 90 | .289 | .725 | | | | | | | JC | Trinidad State Junior College (Trinidad, CO) |
| 1991 | 11 | | 299 | FrRnd | 18 | Dodgers | Chris Latham (minors) | -1.0 | 110 | 213 | 3 | .202 | .557 | | | | | | | HS | Basic HS (Henderson, NV) |
| 1991 | 11 | | 307 | FrRnd | 26 | Athletics | Jason Wood (minors) | 0.1 | 153 | 200 | 5 | .245 | .671 | 1 | 0 | 0 | 0.00 | 0.00 | 0 | 4Yr | California State University Fresno (Fresno, CA) |
| 1991 | 12 | | 312 | FrRnd | 5 | Brewers | Paul Arredondo (minors) | | | | | | | | | | | | | HS | Colton HS (Colton, CA) |
| 1991 | 12 | | 317 | FrRnd | 10 | Phillies | John Mallee (minors) | | | | | | | | | | | | | 4Yr | University of Illinois at Chicago (Chicago, IL) |
| 1991 | 12 | | 320 | FrRnd | 13 | Indians | Jeffery Whitaker (minors) | | | | | | | | | | | | | HS | Martinsville HS (Martinsville, VA) |
| 1991 | 12 | | 332 | FrRnd | 25 | White Sox | Doug Brady (minors) | 0.2 | 12 | 21 | 0 | .190 | .499 | | | | | | | 4Yr | Liberty University (Lynchburg, VA) |
| 1991 | 13 | | 348 | FrRnd | 15 | Tigers | Evan Pratte (minors) | | | | | | | | | | | | | 4Yr | Missouri State University (Springfield, MO) |
| 1991 | 13 | | 354 | FrRnd | 21 | Blue Jays | Alex Gonzalez (minors) | 11.1 | 1396 | 4977 | 137 | .243 | .694 | | | | | | | HS | Killian HS (Miami, FL) |
| 1991 | 14 | | 370 | FrRnd | 11 | Mariners | Raul Rodarte (minors) | | | | | | | | | | | | | JC | Rancho Santiago College (Santa Ana, CA) |
| 1991 | 14 | | 379 | FrRnd | 20 | Reds | Brian Koelling (minors) | -0.4 | 7 | 15 | 0 | .067 | .192 | | | | | | | 4Yr | Bowling Green State University (Bowling Green, OH) |
| 1991 | 14 | | 384 | FrRnd | 25 | White Sox | Glenn Disarcina (minors) | | | | | | | | | | | | | 4Yr | University of Massachusetts Amherst (Amherst, MA) |
| 1991 | 15 | | 394 | FrRnd | 9 | Orioles | Lamann Washington (minors) | | | | | | | | | | | | | HS | Beaufort HS (Beaufort, SC) |
| 1991 | 15 | | 398 | FrRnd | 13 | Indians | Tommy Bates (minors) | | | | | | | | | | | | | 4Yr | University of Louisiana at Lafayette (Lafayette, LA) |
| 1991 | 15 | | 401 | FrRnd | 16 | Giants | Randy Swank (minors) | | | | | | | | | | | | | JC | American River College (Sacramento, CA) |
| 1991 | 16 | | 420 | FrRnd | 9 | Orioles | Derek Adams (minors) | | | | | | | | | | | | | JC | Louisburg College (Louisburg, NC) |
| 1991 | 16 | | 423 | FrRnd | 12 | Cubs | Chad Tredaway (minors) | | | | | | | | | | | | | JC | Seminole Community College (Sanford, FL) |
| 1991 | 16 | | 427 | FrRnd | 16 | Giants | David Rosato (minors) | | | | | | | | | | | | | HS | South HS (Torrance, CA) |
| 1991 | 17 | | 441 | FrRnd | 4 | Cardinals | Ron Warner (minors) | | | | | | | | | | | | | 4Yr | University of Wyoming (Laramie, WY) |
| 1991 | 17 | | 449 | FrRnd | 12 | Cubs | Mitchell Root (minors) | | | | | | | | | | | | | HS | Chatsworth HS (Chatsworth, CA) |
| 1991 | 17 | | 462 | FrRnd | 25 | White Sox | Marc Harris (minors) | | | | | | | | | | | | | HS | Caesar Rodney HS (Camden, DE) |
| 1991 | 18 | | 474 | FrRnd | 11 | Mariners | Craig Bryant (minors) | | | | | | | | | | | | | 4Yr | University of North Alabama (Florence, AL) |
| 1991 | 19 | | 490 | FrRnd | 1 | Yankees | Roger Burnett (minors) | | | | | | | | | | | | | 4Yr | Stanford University (Palo Alto, CA) |
| 1991 | 21 | | 545 | FrRnd | 4 | Cardinals | Jeff Meszar (minors) | | | | | | | | | | | | | JC | Butler County Community College (El Dorado, KS) |
| 1991 | 21 | | 554 | FrRnd | 13 | Indians | Jed Hansen (minors) | -0.3 | 87 | 176 | 4 | .256 | .717 | | | | | | | HS | Capital HS (Olympia, WA) |
| 1991 | 21 | | 558 | FrRnd | 17 | Angels | Keith Stafford (minors) | | | | | | | | | | | | | JC | South Georgia College (Douglas, GA) |
| 1991 | 23 | | 594 | FrRnd | 1 | Yankees | Stephen Anderson (minors) | | | | | | | | | | | | | 4Yr | San Jose State University (San Jose, CA) |
| 1991 | 23 | | 599 | FrRnd | 6 | Astros | Kirk Larson (minors) | | | | | | | | | | | | | HS | Homestead HS (Sunnyvale, CA) |
| 1991 | 23 | | 609 | FrRnd | 16 | Giants | Craig Wilson (minors) | 1.2 | 139 | 372 | 7 | .272 | .704 | | | | | | | 4Yr | Kansas State University (Manhattan, KS) |
| 1991 | 24 | | 621 | FrRnd | 2 | Braves | Sequinn Leichmon (minors) | | | | | | | | | | | | | HS | Strong HS (Strong, AZ) |
| 1991 | 24 | | 630 | FrRnd | 11 | Mariners | Paul London (minors) | | | | | | | | | | | | | HS | Bethel HS (Hampton, VA) |
| 1991 | 24 | | 642 | FrRnd | 23 | Red Sox | Ryan Beeney (minors) | | | | | | | | | | | | | HS | Newark HS (Newark, OH) |
| 1991 | 25 | | 651 | FrRnd | 6 | Astros | Jose Flores (minors) | -0.1 | 16 | 7 | 0 | .143 | .543 | | | | | | | HS | Brandeis HS (New York, NY) |
| 1991 | 27 | | 706 | FrRnd | 9 | Orioles | Jamie Conner (minors) | | | | | | | | | | | | | HS | Hedgesville HS (Martinsburg, WV) |
| 1991 | 27 | | 712 | FrRnd | 15 | Tigers | Victor Rodriguez (minors) | | | | | | | | | | | | | HS | Woodham HS (Pensacola, FL) |
| 1991 | 28 | | 724 | FrRnd | 1 | Yankees | Christopher Heaps (minors) | | | | | | | | | | | | | JC | Gadsden State Community College (Gadsden, AL) |
| 1991 | 28 | | 737 | FrRnd | 14 | Expos | Darrell O'Brien (minors) | | | | | | | | | | | | | HS | Ontario HS (Ontario, CA) |
| 1991 | 29 | | 761 | FrRnd | 12 | Cubs | Rudolph Gomez (minors) | | | | | | | | | | | | | 4Yr | California Baptist University (Riverside, CA) |
| 1991 | 29 | | 769 | FrRnd | 20 | Reds | Scott Snead (minors) | | | | | | | | | | | | | 4Yr | North Carolina State University (Raleigh, NC) |
| 1991 | 29 | | 773 | FrRnd | 24 | Pirates | Ronald Ducksworth (minors) | | | | | | | | | | | | | JC | Mississippi Gulf Coast Community College (Perkinston, MS) |
| 1991 | 30 | | 786 | FrRnd | 11 | Mariners | Edward Odom (minors) | | | | | | | | | | | | | HS | Atlantic HS (Delray Beach, FL) |
| 1991 | 30 | | 790 | FrRnd | 15 | Tigers | Kevin Morgan (minors) | -0.0 | 1 | 1 | 0 | .000 | .000 | | | | | | | 4Yr | Southeastern Louisiana University (Hammond, LA) |
| 1991 | 30 | | 798 | FrRnd | 23 | Red Sox | Chris Wiggs (minors) | | | | | | | | | | | | | HS | Santa Fe Catholic HS (Lakeland, FL) |
| 1991 | 32 | | 847 | FrRnd | 20 | Reds | Matt Cesare (minors) | | | | | | | | | | | | | HS | J.J. Pearce HS (Richardson, TX) |
| 1991 | 33 | | 855 | FrRnd | 2 | Braves | Phil Hollis (minors) | | | | | | | | | | | | | 4Yr | Purdue University (West Lafayette, IN) |
| 1991 | 33 | | 873 | FrRnd | 20 | Reds | Kevin Zellers (minors) | | | | | | | | | | | | | HS | Holy Name HS (Parma Heights, OH) |
| 1991 | 33 | | 877 | FrRnd | 24 | Pirates | Felix Merced (minors) | | | | | | | | | | | | | | |
| 1991 | 34 | | 881 | FrRnd | 2 | Braves | Richard O'Neill (minors) | | | | | | | | | | | | | 4Yr | Illinois State University (Normal, IL) |
| 1991 | 34 | | 890 | FrRnd | 11 | Mariners | Mike Martin (minors) | | | | | | | | | | | | | HS | Maclay HS (Tallahassee, FL) |
| 1991 | 34 | | 895 | FrRnd | 16 | Giants | Juan Johnson (minors) | | | | | | | | | | | | | HS | Thomas Stone HS (Waldorf, MD) |
| 1991 | 34 | | 901 | FrRnd | 22 | Mets | Travis Ryan (minors) | | | | | | | | | | | | | JC | Labette Community College (Parsons, KS) |
| 1991 | 35 | | 916 | FrRnd | 11 | Mariners | Steve McNair (minors) | | | | | | | | | | | | | HS | Mount Olive HS (Mount Olive, MS) |
| 1991 | 35 | | 922 | FrRnd | 17 | Angels | Glenn Duckett (minors) | | | | | | | | | | | | | HS | Carthage HS (Carthage, MO) |
| 1991 | 35 | | 923 | FrRnd | 18 | Dodgers | Ed Acosta (minors) | | | | | | | | | | | | | HS | Rock Falls HS (Rock Falls, IL) |
| 1991 | 36 | | 943 | FrRnd | 12 | Cubs | Ramon Martinez (minors) | | | | | | | | | | | | | | |
| 1991 | 37 | | 958 | FrRnd | 1 | Yankees | Ron Hollis (minors) | | | | | | | | | | | | | HS | Brighton HS (Brighton, MI) |
| 1991 | 37 | | 974 | FrRnd | 17 | Angels | Dee Dalton (minors) | | | | | | | | | | | | | HS | Cave Spring HS (Roanoke, VA) |
| 1991 | 38 | | 995 | FrRnd | 12 | Cubs | Curtis Hall (minors) | | | | | | | | | | | | | HS | Pocatello HS (Pocatello, ID) |
| 1991 | 38 | | 1006 | FrRnd | 23 | Red Sox | Steve Carver (minors) | | | | | | | | | | | | | HS | Bolles HS (Jacksonville, FL) |
| 1991 | 39 | | 1010 | FrRnd | 1 | Yankees | David Renteria (minors) | | | | | | | | | | | | | JC | Riverside Community College (Riverside, CA) |
| 1991 | 39 | | 1020 | FrRnd | 11 | Mariners | Kevin Faircloth (minors) | | | | | | | | | | | | | HS | Glenn HS (Winston-Salem, NC) |
| 1991 | 39 | | 1028 | FrRnd | 19 | Rangers | Kevin Sisk (minors) | | | | | | | | | | | | | 4Yr | James Madison University (Harrisonburg, VA) |
| 1991 | 40 | | 1041 | FrRnd | 6 | Astros | Mike Metcalfe (minors) | -0.2 | 8 | 13 | 0 | .077 | .220 | | | | | | | HS | Colonial HS (Orlando, FL) |
| 1991 | 40 | | 1050 | FrRnd | 15 | Tigers | Ricky Martinez (minors) | | | | | | | | | | | | | JC | College of the Desert (Palm Desert, CA) |
| 1991 | 41 | | 1072 | FrRnd | 12 | Cubs | Daron Mooneyharn (minors) | | | | | | | | | | | | | HS | Mammoth HS (Mammoth Lakes, CA) |
| 1991 | 42 | | 1098 | FrRnd | 13 | Indians | Erik Lane (minors) | | | | | | | | | | | | | HS | Russellville HS (Russellville, AR) |
| 1991 | 42 | | 1102 | FrRnd | 17 | Angels | Freddie Diaz (minors) | | | | | | | | | | | | | JC | Pasadena City College (Pasadena, CA) |
| 1991 | 42 | | 1105 | FrRnd | 20 | Reds | Dee Jenkins (minors) | | | | | | | | | | | | | HS | Dreher HS (Columbia, SC) |
| 1991 | 42 | | 1106 | FrRnd | 21 | Blue Jays | Andy Srebroski (minors) | | | | | | | | | | | | | JC | Anne Arundel Community College (Arnold, MD) |
| 1991 | 42 | | 1107 | FrRnd | 22 | Mets | Kenneth Bradley (minors) | | | | | | | | | | | | | HS | Dollarway HS (Pine Bluff, AR) |
| 1991 | 43 | | 1119 | FrRnd | 9 | Orioles | Jeff Ferguson (minors) | | | | | | | | | | | | | HS | La Serna HS (Whittier, CA) |
| 1991 | 43 | | 1126 | FrRnd | 16 | Giants | J.T. Messick (minors) | | | | | | | | | | | | | HS | Tulsa Union HS (Tulsa, OK) |
| 1991 | 43 | | 1127 | FrRnd | 17 | Angels | Aaron Boone (minors) | 13.5 | 1152 | 3871 | 126 | .263 | .751 | | | | | | | HS | Villa Park HS (Villa Park, CA) |
| 1991 | 43 | | 1130 | FrRnd | 20 | Reds | Jimmy Rice (minors) | | | | | | | | | | | | | HS | McLean County HS (Owensboro, KY) |
| 1991 | 43 | | 1134 | FrRnd | 24 | White Sox | Mike Eaglin (minors) | | | | | | | | | | | | | HS | De Anza HS (Richmond, CA) |
| 1991 | 44 | | 1146 | FrRnd | 11 | Mariners | Chris Gorr (minors) | | | | | | | | | | | | | HS | Rancho Buena Vista HS (Vista, CA) |
| 1991 | 44 | | 1148 | FrRnd | 13 | Indians | Damian Jackson (minors) | 6.7 | 827 | 2209 | 32 | .243 | .679 | | | | | | | HS | Ygnacio Valley HS (Concord, CA) |
| 1991 | 45 | | 1171 | FrRnd | 11 | Mariners | John Thompson (minors) | | | | | | | | | | | | | HS | Shadle Park HS (Spokane, WA) |
| 1991 | 45 | | 1178 | FrRnd | 18 | Dodgers | Marc Tramuta (minors) | | | | | | | | | | | | | 4Yr | St. Bonaventure University (St. Bonaventure, NY) |
| 1991 | 45 | | 1184 | FrRnd | 24 | White Sox | Shannon Coulter (minors) | | | | | | | | | | | | | HS | Grand Prairie HS (Grand Prairie, TX) |
| 1991 | 46 | | 1203 | FrRnd | 18 | Dodgers | Mario Moody (minors) | | | | | | | | | | | | | HS | Glynn Academy HS (Brunswick, GA) |
| 1991 | 47 | | 1219 | FrRnd | 9 | Orioles | Chris Pageau (minors) | | | | | | | | | | | | | JC | Schenectady County CC (Schenectady, NY) |
| 1991 | 47 | | 1224 | FrRnd | 14 | Expos | Jon Valenti (minors) | | | | | | | | | | | | | HS | Highland HS (Bakersfield, CA) |
| 1991 | 48 | | 1240 | FrRnd | 5 | Astros | Paul Barber (minors) | | | | | | | | | | | | | HS | Queen City HS (Queen City, TX) |
| 1991 | 48 | | 1243 | FrRnd | 8 | Orioles | Matthew Reimer (minors) | | | | | | | | | | | | | HS | Patapsco HS (Dundalk, MD) |
| 1991 | 48 | | 1246 | FrRnd | 11 | Indians | Shannon Jones (minors) | | | | | | | | | | | | | JC | New Mexico Junior College (Hobbs, NM) |
| 1991 | 48 | | 1248 | FrRnd | 13 | Tigers | Tristan Paul (minors) | | | | | | | | | | | | | HS | Rolling Hills HS (Rolling Hills Estates, CA) |
| 1991 | 48 | | 1250 | FrRnd | 15 | Angels | Rudolph Stroud (minors) | | | | | | | | | | | | | HS | Brandon HS (Brandon, FL) |
| 1991 | 49 | | 1267 | FrRnd | 9 | Mariners | Tyson Kimm (minors) | | | | | | | | | | | | | HS | Norway HS (Norway, IA) |
| 1991 | 49 | | 1276 | FrRnd | 18 | Blue Jays | Emanuel Hayes (minors) | | | | | | | | | | | | | JC | Odessa College (Odessa, TX) |
| 1991 | 50 | | 1293 | FrRnd | 13 | Angels | Allan Parker (minors) | | | | | | | | | | | | | JC | Polk Community College (Winter Haven, FL) |
| 1991 | 50 | | 1299 | FrRnd | 19 | Pirates | Clyde Earl (minors) | | | | | | | | | | | | | 4Yr | Chicago State University (Chicago, IL) |
| 1991 | 50 | | 1300 | FrRnd | 20 | White Sox | Bobby Langer (minors) | | | | | | | | | | | | | 4Yr | Creighton University (Omaha, NE) |
| 1991 | 51 | | 1316 | FrRnd | 15 | Rangers | Todd Walker (minors) | 10.5 | 1288 | 4554 | 107 | .289 | .783 | | | | | | | HS | Airline HS (Bossier City, LA) |
| 1991 | 51 | | 1317 | FrRnd | 16 | Reds | Steve Claybrook (minors) | | | | | | | | | | | | | HS | Calallen HS (Corpus Christi, TX) |
| 1991 | 51 | | 1318 | FrRnd | 17 | Blue Jays | Symmion Willis (minors) | | | | | | | | | | | | | HS | Mays HS (Atlanta, GA) |
| 1991 | 52 | | 1341 | FrRnd | 19 | White Sox | Shawn McGinn (minors) | | | | | | | | | | | | | 4Yr | University of Nebraska at Omaha (Omaha, NE) |
| 1991 | 53 | | 1358 | FrRnd | 16 | Blue Jays | Vick Brown (minors) | | | | | | | | | | | | | HS | Grand Ridge HS (Cypress, FL) |
| 1991 | 54 | | 1376 | FrRnd | 15 | Blue Jays | Cuba Gregory (minors) | | | | | | | | | | | | | HS | Southeastern HS (Detroit, MI) |
| 1991 | 56 | | 1396 | FrRnd | 1 | Yankees | Mark Dean (minors) | | | | | | | | | | | | | JC | Florida College (Jacksonville, FL) |
| 1991 | 56 | | 1404 | FrRnd | 9 | Expos | Russ White (minors) | | | | | | | | | | | | | HS | Hale HS (Tulsa, OK) |
| 1991 | 56 | | 1409 | FrRnd | 14 | Blue Jays | Les Dennis (minors) | | | | | | | | | | | | | HS | West Linn HS (West Linn, OR) |
| 1991 | 58 | | 1440 | FrRnd | 14 | Pirates | Scott Krause (minors) | | | | | | | | | | | | | HS | North HS (Willowick, OH) |
| 1991 | 60 | | 1453 | FrRnd | 1 | Yankees | Kelvin Washington (minors) | | | | | | | | | | | | | HS | Westwood HS (Fort Pierce, FL) |
| 1991 | 60 | | 1461 | FrRnd | 9 | Tigers | Kerry Collins (minors) | | | | | | | | | | | | | 4Yr | Pennsylvania State University (State College, PA) |
| 1991 | 62 | | 1483 | FrRnd | 7 | Indians | Tim Thompson (minors) | | | | | | | | | | | | | HS | Harding HS (Charlotte, NC) |
| 1991 | 63 | | 1489 | FrRnd | 1 | Yankees | Jason Birmingham (minors) | | | | | | | | | | | | | HS | St. Patrick's HS (Sarnia, ON) |
| 1991 | 65 | | 1511 | FrRnd | 7 | Dodgers | David Silvas (minors) | | | | | | | | | | | | | HS | San Jacinto HS (Pearland, TX) |
| 1991 | 67 | | 1519 | FrRnd | 1 | Yankees | Kory Kiper (minors) | | | | | | | | | | | | | HS | Wellington Community HS (Wellington, FL) |
| 1991 | 67 | | 1522 | FrRnd | 4 | Mariners | Darian Hagan (minors) | | | | | | | | | | | | | 4Yr | University of Colorado (Boulder, CO) |
| 1991 | 68 | | 1528 | FrRnd | 3 | Expos | Dan DiPace (minors) | | | | | | | | | | | | | HS | Martin County HS (Stuart, FL) |
| 1991 | 73 | | 1549 | FrRnd | 3 | Dodgers | Stephane DiLauro (minors) | | | | | | | | | | | | | HS | Academy Laval Bib (Montreal, QC) |
| 1991 | 75 | | 1553 | FrRnd | 1 | Yankees | Brent Hall (minors) | | | | | | | | | | | | | HS | Willow Creek HS (Claresholm, AB) |
| 1991 | 79 | | 1567 | FrRnd | 3 | Dodgers | Stephen Matyczyk (minors) | | | | | | | | | | | | | HS | Southington HS (Southington, CT) |
| 1991 | 81 | | 1572 | FrRnd | 2 | Dodgers | Gar Vallone (minors) | | | | | | | | | | | | | HS | El Dorado HS (Placentia, CA) |
| 1991 | 83 | | 1576 | FrRnd | 2 | Dodgers | Aaron Wofford (minors) | | | | | | | | | | | | | JC | Yuba CC (Marysvale, CA) |
| 1991 | 92 | | 1593 | FrRnd | 1 | Astros | Mike Hammer (minors) | | | | | | | | | | | | | HS | Willowbrook HS (Villa Park, IL) |
| 1991 | 94 | | 1598 | FrRnd | 2 | Dodgers | Shawn McNally (minors) | | | | | | | | | | | | | HS | Winder-Barrow HS (Winder, GA) |