| 1966 | 1 | | 3 | FrRnd | 3 | Astros | Wayne Twitchell (minors) | 2.2 | 282 | 260 | 0 | .127 | .310 | 282 | 48 | 65 | 3.98 | 1.43 | 2 | HS | Woodrow Wilson HS (Portland, OR) |
| 1966 | 1 | | 5 | FrRnd | 5 | Cubs | Dean Burk (minors) | | | | | | | | | | | | | HS | Highland HS (Highland, IL) |
| 1966 | 1 | | 9 | FrRnd | 9 | Phillies | Michael Biko (minors) | | | | | | | | | | | | | HS | W.W. Samuel HS (Dallas, TX) |
| 1966 | 1 | | 11 | FrRnd | 11 | Braves | Al Santorini (minors) | 0.2 | 127 | 137 | 1 | .109 | .278 | 127 | 17 | 38 | 4.29 | 1.47 | 3 | HS | Union HS (Union, NJ) |
| 1966 | 1 | | 13 | FrRnd | 13 | Reds | Gary Nolan (minors) | 25.9 | 252 | 529 | 1 | .138 | .371 | 250 | 110 | 70 | 3.08 | 1.15 | 0 | HS | Oroville HS (Oroville, CA) |
| 1966 | 1 | | 17 | FrRnd | 17 | Giants | Bob Reynolds (minors) | 2.9 | 140 | 4 | 0 | .000 | .000 | 140 | 14 | 16 | 3.15 | 1.32 | 21 | HS | Ingraham HS (Seattle, WA) |
| 1966 | 1 | | 19 | FrRnd | 19 | Dodgers | Lawrence Hutton (minors) | | | | | | | | | | | | | HS | Greenfield HS (Greenfield, IN) |
| 1966 | 2 | | 21 | FrRnd | 1 | Mets | Byron Von Hoff (minors) | | | | | | | | | | | | | HS | Batavia HS (Batavia, IL) |
| 1966 | 2 | | 28 | FrRnd | 8 | Angels | David Frost (minors) | | | | | | | | | | | | | HS | Lawton HS (Lawton, OK) |
| 1966 | 2 | | 35 | FrRnd | 15 | Pirates | Jim Minshall (minors) | 0.1 | 6 | 0 | 0 | | | 6 | 0 | 1 | 0.00 | 0.94 | 0 | HS | Newport Catholic HS (Melbourne, KY) |
| 1966 | 3 | | 43 | FrRnd | 3 | Astros | John D'Auria (minors) | | | | | | | | | | | | | HS | Arcadia HS (Arcadia, CA) |
| 1966 | 3 | | 47 | FrRnd | 7 | Cardinals | Clay Kirby (minors) | 7.1 | 265 | 478 | 0 | .098 | .265 | 261 | 75 | 104 | 3.84 | 1.38 | 0 | HS | Washington HS (Arlington, VA) |
| 1966 | 3 | | 48 | FrRnd | 8 | Angels | Bill Gillean (minors) | | | | | | | | | | | | | HS | Mayfair HS (Lakewood, CA) |
| 1966 | 3 | | 53 | FrRnd | 13 | Reds | Mike Oates (minors) | | | | | | | | | | | | | HS | Glenbard West HS (Glen Ellyn, IL) |
| 1966 | 3 | | 55 | FrRnd | 15 | Pirates | Dick Grimaldi (minors) | | | | | | | | | | | | | HS | Proctor HS (Utica, NY) |
| 1966 | 3 | | 57 | FrRnd | 17 | Giants | James Carroll (minors) | | | | | | | | | | | | | 4Yr | Mississippi State University (Mississippi State, MS) |
| 1966 | 4 | | 66 | FrRnd | 6 | Senators | Wallace Smallwood (minors) | | | | | | | | | | | | | HS | Martinsburg HS (Martinsburg, WV) |
| 1966 | 5 | | 81 | FrRnd | 1 | Mets | Richard Dost (minors) | | | | | | | | | | | | | HS | James Madison HS (Vienna, VA) |
| 1966 | 5 | | 87 | FrRnd | 7 | Cardinals | Don Cooksey (minors) | | | | | | | | | | | | | HS | O'Fallon Tech (St. Louis, MO) |
| 1966 | 5 | | 90 | FrRnd | 10 | Yankees | Carl Black (minors) | | | | | | | | | | | | | 4Yr | University of Central Missouri (Warrensburg, MO) |
| 1966 | 5 | | 93 | FrRnd | 13 | Reds | Richard Washburn (minors) | | | | | | | | | | | | | 4Yr | University of St. Thomas (St. Paul, MN) |
| 1966 | 6 | | 101 | FrRnd | 1 | Mets | Edward Lindblad (minors) | | | | | | | | | | | | | HS | Piper HS (Piper, KS) |
| 1966 | 6 | | 104 | FrRnd | 4 | Red Sox | Mike Nagy (minors) | 2.1 | 88 | 133 | 0 | .135 | .352 | 87 | 20 | 13 | 4.15 | 1.53 | 0 | HS | St. Helena HS (Bronx, NY) |
| 1966 | 6 | | 106 | FrRnd | 6 | Senators | Kim Hillstrom (minors) | | | | | | | | | | | | | 4Yr | Central Michigan University (Mount Pleasant, MI) |
| 1966 | 6 | | 109 | FrRnd | 9 | Phillies | Michael Beaver (minors) | | | | | | | | | | | | | HS | Worland HS (Worland, WY) |
| 1966 | 6 | | 113 | FrRnd | 13 | Reds | Stephen Steitz (minors) | | | | | | | | | | | | | HS | East Longmeadow HS (East Longmeadow, MA) |
| 1966 | 7 | | 126 | FrRnd | 6 | Senators | John Fryer (minors) | | | | | | | | | | | | | JC | Brevard Community College (Cocoa, FL) |
| 1966 | 7 | | 128 | FrRnd | 8 | Angels | Robert Smith (minors) | | | | | | | | | | | | | 4Yr | St. John's University (Queens, NY) |
| 1966 | 7 | | 129 | FrRnd | 9 | Phillies | William Camp (minors) | | | | | | | | | | | | | HS | Hale HS (Tulsa, OK) |
| 1966 | 7 | | 130 | FrRnd | 10 | Yankees | Steve Kline (minors) | 6.9 | 129 | 170 | 0 | .124 | .320 | 129 | 43 | 45 | 3.26 | 1.19 | 1 | HS | Chelan HS (Chelan, WA) |
| 1966 | 7 | | 133 | FrRnd | 13 | Reds | Dave Grawe (minors) | | | | | | | | | | | | | HS | Elder HS (Cincinnati, OH) |
| 1966 | 7 | | 136 | FrRnd | 16 | Orioles | Ronald Norris (minors) | | | | | | | | | | | | | HS | Hillcrest HS (Springfield, MO) |
| 1966 | 7 | | 137 | FrRnd | 17 | Giants | John Beaton (minors) | | | | | | | | | | | | | 4Yr | Murray State University (Murray, KY) |
| 1966 | 7 | | 140 | FrRnd | 20 | Twins | Robert Weisenberg (minors) | | | | | | | | | | | | | HS | North HS (Omaha, NE) |
| 1966 | 8 | | 142 | FrRnd | 2 | Athletics | Thomas Brooks (minors) | | | | | | | | | | | | | HS | St. James HS (Chester, PA) |
| 1966 | 8 | | 150 | FrRnd | 10 | Yankees | Michael McFarland (minors) | | | | | | | | | | | | | 4Yr | University of Missouri Columbia (Columbia, MO) |
| 1966 | 8 | | 151 | FrRnd | 11 | Braves | Gerald Hurt (minors) | | | | | | | | | | | | | 4Yr | University of Missouri Columbia (Columbia, MO) |
| 1966 | 9 | | 162 | FrRnd | 2 | Athletics | Frank Fall (minors) | | | | | | | | | | | | | HS | McClatchy HS (Sacramento, CA) |
| 1966 | 9 | | 165 | FrRnd | 5 | Cubs | John Miller (minors) | | | | | | | | | | | | | HS | I.H.M. Academy HS (Coeur D'Alene, ID) |
| 1966 | 9 | | 168 | FrRnd | 8 | Angels | Ken Forsch (minors) | 26.4 | 521 | 383 | 0 | .136 | .322 | 521 | 114 | 113 | 3.37 | 1.25 | 51 | JC | Sacramento City College (Sacramento, CA) |
| 1966 | 9 | | 173 | FrRnd | 13 | Reds | David Reeves (minors) | | | | | | | | | | | | | HS | Americus HS (Americus, GA) |
| 1966 | 9 | | 180 | FrRnd | 20 | Twins | James Needham (minors) | | | | | | | | | | | | | HS | Loomis Chaffee HS (Windsor, CT) |
| 1966 | 10 | | 181 | FrRnd | 1 | Mets | Russ Vitallo (minors) | | | | | | | | | | | | | JC | Berkshire CC (Pittsfield, MA) |
| 1966 | 10 | | 182 | FrRnd | 2 | Athletics | Nick Radakovic (minors) | | | | | | | | | | | | | 4Yr | University of Michigan (Ann Arbor, MI) |
| 1966 | 10 | | 193 | FrRnd | 13 | Reds | Jeff Pryor (minors) | | | | | | | | | | | | | HS | Evans HS (Orlando, FL) |
| 1966 | 10 | | 194 | FrRnd | 14 | Tigers | Brian Cusino (minors) | | | | | | | | | | | | | HS | Monroe Catholic Central HS (Erie, MI) |
| 1966 | 11 | | 203 | FrRnd | 3 | Astros | John Caruso (minors) | | | | | | | | | | | | | HS | Franklin K. Lane HS (Ozone Park, NY) |
| 1966 | 11 | | 208 | FrRnd | 8 | Angels | Jim Barr (minors) | 31.1 | 481 | 513 | 1 | .162 | .396 | 454 | 101 | 112 | 3.56 | 1.28 | 12 | HS | Lynwood HS (Lynwood, CA) |
| 1966 | 11 | | 214 | FrRnd | 14 | Tigers | Bob Kloss (minors) | | | | | | | | | | | | | HS | St. Ladislaus HS (Detroit, MI) |
| 1966 | 11 | | 215 | FrRnd | 15 | Pirates | Dave Arrington (minors) | | | | | | | | | | | | | HS | De Anza HS (Richmond, CA) |
| 1966 | 12 | | 224 | FrRnd | 4 | Red Sox | Tom Stephenson (minors) | | | | | | | | | | | | | | |
| 1966 | 12 | | 227 | FrRnd | 7 | Cardinals | Joe Atilee (minors) | | | | | | | | | | | | | HS | Elmore HS (Houston, TX) |
| 1966 | 12 | | 230 | FrRnd | 10 | Yankees | Bill Fisher (minors) | | | | | | | | | | | | | HS | Tahlequah HS (Tahlequah, OK) |
| 1966 | 12 | | 233 | FrRnd | 13 | Reds | Edward Robbins (minors) | | | | | | | | | | | | | HS | Hillsboro HS (Hillsboro, OH) |
| 1966 | 12 | | 235 | FrRnd | 15 | Pirates | Ron Schueler (minors) | 3.7 | 292 | 170 | 0 | .159 | .352 | 291 | 40 | 48 | 4.08 | 1.37 | 11 | HS | Hays HS (Hays, KS) |
| 1966 | 13 | | 243 | FrRnd | 3 | Astros | Douglas Hansen (minors) | | | | | | | | | | | | | HS | Hoover HS (Fresno, CA) |
| 1966 | 13 | | 248 | FrRnd | 8 | Angels | Anthony Mitchell (minors) | | | | | | | | | | | | | HS | Abraham Lincoln HS (San Diego, CA) |
| 1966 | 13 | | 249 | FrRnd | 9 | Phillies | Smith Holland (minors) | | | | | | | | | | | | | 4Yr | The Citadel (Charleston, SC) |
| 1966 | 13 | | 250 | FrRnd | 10 | Yankees | Kenneth O'Brien (minors) | | | | | | | | | | | | | HS | Hewlett HS (Woodmere, NY) |
| 1966 | 13 | | 251 | FrRnd | 11 | Braves | Buddy Harris (minors) | -0.5 | 22 | 3 | 0 | .000 | .000 | 22 | 1 | 1 | 6.32 | 1.49 | 0 | HS | Roxborough HS (Philadelphia, PA) |
| 1966 | 13 | | 252 | FrRnd | 12 | Indians | Billy Ray Palmer (minors) | | | | | | | | | | | | | 4Yr | Rice University (Houston, TX) |
| 1966 | 13 | | 255 | FrRnd | 15 | Pirates | Raymond Heller (minors) | | | | | | | | | | | | | HS | Wicomico HS (Salisbury, MD) |
| 1966 | 14 | | 266 | FrRnd | 6 | Senators | Dan Neumeier (minors) | -0.1 | 3 | 1 | 0 | .000 | .000 | 3 | 0 | 0 | 9.00 | 1.67 | 0 | HS | Gresham HS (Gresham, WI) |
| 1966 | 14 | | 267 | FrRnd | 7 | Cardinals | Douglas Lukens (minors) | | | | | | | | | | | | | 4Yr | Washington State University (Pullman, WA) |
| 1966 | 14 | | 268 | FrRnd | 8 | Angels | Paul DeVaney (minors) | | | | | | | | | | | | | HS | DeSales HS (Geneva, NY) |
| 1966 | 14 | | 269 | FrRnd | 9 | Phillies | Jack Foreman (minors) | | | | | | | | | | | | | HS | Shelby HS (Shelby, OH) |
| 1966 | 14 | | 271 | FrRnd | 11 | Braves | John Stewart (minors) | | | | | | | | | | | | | 4Yr | University of Southern California (Los Angeles, CA) |
| 1966 | 14 | | 274 | FrRnd | 14 | Tigers | Herbert Doebler (minors) | | | | | | | | | | | | | HS | Utica HS (Utica, MI) |
| 1966 | 14 | | 279 | FrRnd | 19 | Dodgers | James Raynor (minors) | | | | | | | | | | | | | 4Yr | East Carolina University (Greenville, NC) |
| 1966 | 14 | | 280 | FrRnd | 20 | Twins | Bruce Wade (minors) | | | | | | | | | | | | | HS | North Torrance HS (Torrance, CA) |
| 1966 | 15 | | 282 | FrRnd | 2 | Athletics | Darrell Baker (minors) | | | | | | | | | | | | | HS | Holbrook HS (Holbrook, MA) |
| 1966 | 15 | | 283 | FrRnd | 3 | Astros | Michael Cole (minors) | | | | | | | | | | | | | JC | Southern Baptist JC (Walnut Ridge, AR) |
| 1966 | 15 | | 286 | FrRnd | 6 | Senators | Geoff Petrie (minors) | | | | | | | | | | | | | HS | Springfield HS (Springfield, PA) |
| 1966 | 15 | | 289 | FrRnd | 9 | Phillies | Frederick Grooms (void) | | | | | | | | | | | | | HS | Wilson HS (San Francisco, CA) |
| 1966 | 15 | | 292 | FrRnd | 12 | Indians | James Wingate (minors) | | | | | | | | | | | | | 4Yr | Trinity University (San Antonio, TX) |
| 1966 | 15 | | 293 | FrRnd | 13 | Reds | Thomas Henderson (minors) | | | | | | | | | | | | | 4Yr | Northeastern State University (Tahlequah, OK) |
| 1966 | 15 | | 296 | FrRnd | 16 | Orioles | Richard Rhine (minors) | | | | | | | | | | | | | 4Yr | Pennsylvania State University (State College, PA) |
| 1966 | 15 | | 298 | FrRnd | 18 | White Sox | Mike Thompson (minors) | -0.8 | 54 | 41 | 0 | .098 | .257 | 54 | 1 | 15 | 4.86 | 1.74 | 0 | HS | Ponca City HS (Ponca City, OK) |
| 1966 | 16 | | 304 | FrRnd | 4 | Red Sox | Ed Phillips (minors) | -0.2 | 18 | 3 | 0 | .000 | .000 | 18 | 0 | 2 | 5.32 | 1.65 | 0 | 4Yr | Colby College (Waterville, ME) |
| 1966 | 16 | | 308 | FrRnd | 8 | Angels | Glen Pickren (minors) | | | | | | | | | | | | | HS | Seminole HS (Seminole, FL) |
| 1966 | 17 | | 324 | FrRnd | 4 | Red Sox | Dennis Udy (minors) | | | | | | | | | | | | | 4Yr | University of Utah (Salt Lake City, UT) |
| 1966 | 17 | | 326 | FrRnd | 6 | Senators | Nicholas Furlong (minors) | | | | | | | | | | | | | HS | Iona Prep HS (Eastchester, NY) |
| 1966 | 17 | | 331 | FrRnd | 11 | Braves | Charlie Brown (minors) | | | | | | | | | | | | | 4Yr | Central Connecticut State University (New Britain, CT) |
| 1966 | 17 | | 333 | FrRnd | 13 | Reds | Claude Passeau (minors) | | | | | | | | | | | | | 4Yr | Mississippi State University (Mississippi State, MS) |
| 1966 | 17 | | 339 | FrRnd | 19 | Dodgers | Kenneth Raab (minors) | | | | | | | | | | | | | HS | Northview HS (Covina, CA) |
| 1966 | 18 | | 357 | FrRnd | 17 | Giants | Dale Spier (minors) | | | | | | | | | | | | | 4Yr | Arizona State University (Tempe, AZ) |
| 1966 | 18 | | 360 | FrRnd | 20 | Twins | Mike Sigman (minors) | | | | | | | | | | | | | HS | Kearny HS (San Diego, CA) |
| 1966 | 19 | | 369 | FrRnd | 9 | Phillies | Richard Corsetto (minors) | | | | | | | | | | | | | 4Yr | Gannon University (Erie, PA) |
| 1966 | 19 | | 373 | FrRnd | 13 | Reds | Robert Orange (minors) | | | | | | | | | | | | | HS | Morgan Park HS (Chicago, IL) |
| 1966 | 19 | | 374 | FrRnd | 14 | Tigers | James Blight (minors) | | | | | | | | | | | | | 4Yr | Michigan State University (East Lansing, MI) |
| 1966 | 19 | | 377 | FrRnd | 17 | Giants | Clifford Farmer (minors) | | | | | | | | | | | | | HS | Hillcrest HS (Springfield, MO) |
| 1966 | 19 | | 379 | FrRnd | 19 | Dodgers | Martin Parker (minors) | | | | | | | | | | | | | HS | King HS (Tampa, FL) |
| 1966 | 20 | | 381 | FrRnd | 1 | Mets | Ernie McAnally (minors) | -0.9 | 112 | 204 | 1 | .132 | .300 | 112 | 30 | 49 | 4.03 | 1.39 | 0 | JC | Paris Junior College (Paris, TX) |
| 1966 | 20 | | 382 | FrRnd | 2 | Athletics | Larry Burchart (minors) | -0.2 | 29 | 0 | 0 | | | 29 | 0 | 2 | 4.25 | 1.56 | 0 | 4Yr | Oklahoma State University (Stillwater, OK) |
| 1966 | 20 | | 384 | FrRnd | 4 | Red Sox | Bernard Linn (minors) | | | | | | | | | | | | | HS | Grossmont HS (El Cajon, CA) |
| 1966 | 20 | | 387 | FrRnd | 7 | Cardinals | Clement Nowakowski (minors) | | | | | | | | | | | | | HS | Washington HS (Chicago, IL) |
| 1966 | 20 | | 393 | FrRnd | 13 | Reds | Rick Henninger (minors) | 0.6 | 6 | 0 | 0 | | | 6 | 1 | 0 | 2.74 | 1.48 | 0 | HS | Hastings HS (Hastings, NE) |
| 1966 | 20 | | 399 | FrRnd | 19 | Dodgers | Loyd Colson (minors) | -0.0 | 1 | 0 | 0 | | | 1 | 0 | 0 | 4.50 | 1.50 | 0 | HS | Gould HS (Gould, OK) |
| 1966 | 21 | | 402 | FrRnd | 2 | Athletics | Bruce Ocken (minors) | | | | | | | | | | | | | HS | Turlock HS (Turlock, CA) |
| 1966 | 21 | | 403 | FrRnd | 3 | Astros | Frank Van Devender (minors) | | | | | | | | | | | | | JC | San Diego Mesa College (San Diego, CA) |
| 1966 | 21 | | 404 | FrRnd | 4 | Red Sox | Eugene Collins (minors) | | | | | | | | | | | | | HS | Choctawhatchee HS (Fort Walton Beach, FL) |
| 1966 | 21 | | 406 | FrRnd | 6 | Senators | Charles Miller (minors) | | | | | | | | | | | | | HS | Waynesville HS (Waynesville, OH) |
| 1966 | 21 | | 408 | FrRnd | 8 | Angels | Irl Davis (minors) | | | | | | | | | | | | | HS | Bishop Montgomery HS (Torrance, CA) |
| 1966 | 21 | | 410 | FrRnd | 10 | Yankees | Julian Karp (minors) | | | | | | | | | | | | | 4Yr | Washington State University (Pullman, WA) |
| 1966 | 21 | | 412 | FrRnd | 12 | Indians | Richard Holliday (minors) | | | | | | | | | | | | | 4Yr | Westminster College (New Wilmington, PA) |
| 1966 | 21 | | 414 | FrRnd | 14 | Tigers | Bob Buchanan (minors) | | | | | | | | | | | | | HS | East HS (Buffalo, NY) |
| 1966 | 21 | | 420 | FrRnd | 20 | Twins | Dan Vossler (minors) | | | | | | | | | | | | | HS | Porterville HS (Porterville, CA) |
| 1966 | 22 | | 423 | FrRnd | 3 | Astros | Bob Watkins (minors) | 0.0 | 5 | 2 | 0 | .000 | .000 | 5 | 0 | 0 | 5.17 | 1.66 | 0 | HS | Compton HS (Compton, CA) |
| 1966 | 22 | | 426 | FrRnd | 6 | Senators | William Kelley (minors) | | | | | | | | | | | | | HS | Archbishop Curley HS (Baltimore, MD) |
| 1966 | 22 | | 427 | FrRnd | 7 | Cardinals | Robert Sharp (minors) | | | | | | | | | | | | | HS | Torrance HS (Torrance, CA) |
| 1966 | 22 | | 428 | FrRnd | 8 | Angels | Lou Mellini (minors) | | | | | | | | | | | | | HS | Beverly Hills HS (Beverly Hills, CA) |
| 1966 | 22 | | 429 | FrRnd | 9 | Phillies | James Sanders (minors) | | | | | | | | | | | | | HS | Southside HS (Florence, SC) |
| 1966 | 22 | | 435 | FrRnd | 15 | Pirates | Larry Stout (minors) | | | | | | | | | | | | | 4Yr | Huntington University (Huntington, IN) |
| 1966 | 22 | | 436 | FrRnd | 16 | Orioles | Daniel Beard (minors) | | | | | | | | | | | | | HS | Lakewood HS (Lakewood, CA) |
| 1966 | 22 | | 439 | FrRnd | 19 | Dodgers | Charles Sutton (minors) | | | | | | | | | | | | | HS | Tate HS (Molino, FL) |
| 1966 | 23 | | 443 | FrRnd | 3 | Astros | William Wright (minors) | | | | | | | | | | | | | HS | South Park HS (Beaumont, TX) |
| 1966 | 23 | | 447 | FrRnd | 7 | Cardinals | Jerry Meadows (minors) | | | | | | | | | | | | | 4Yr | West Virginia University (Morgantown, WV) |
| 1966 | 23 | | 452 | FrRnd | 12 | Indians | Bob Biscan (minors) | | | | | | | | | | | | | HS | Morton HS (Hammond, IN) |
| 1966 | 23 | | 455 | FrRnd | 15 | Pirates | Calvin Bailey (minors) | | | | | | | | | | | | | 4Yr | West Virginia State University (Institute, WV) |
| 1966 | 23 | | 457 | FrRnd | 17 | Giants | Charlie Hopkins (minors) | | | | | | | | | | | | | 4Yr | University of Oregon (Eugene, OR) |
| 1966 | 23 | | 458 | FrRnd | 18 | White Sox | Andrew Thomas (minors) | | | | | | | | | | | | | 4Yr | Indiana State University (Terre Haute, IN) |
| 1966 | 23 | | 459 | FrRnd | 19 | Dodgers | James Frye (minors) | | | | | | | | | | | | | HS | Northern HS (Pontiac, MI) |
| 1966 | 24 | | 461 | FrRnd | 1 | Mets | Frank Lolich (minors) | | | | | | | | | | | | | 4Yr | Brigham Young University (Provo, UT) |
| 1966 | 24 | | 465 | FrRnd | 5 | Cubs | Stephen Hanson (minors) | | | | | | | | | | | | | HS | Saratoga HS (Saratoga, CA) |
| 1966 | 24 | | 466 | FrRnd | 6 | Senators | Michael Flanagan (minors) | | | | | | | | | | | | | 4Yr | University of North Carolina at Chapel Hill (Chapel Hill, NC) |
| 1966 | 24 | | 467 | FrRnd | 7 | Cardinals | Lew Wright (minors) | | | | | | | | | | | | | HS | College Park HS (Pleasant Hill, CA) |
| 1966 | 24 | | 468 | FrRnd | 8 | Angels | Tom Buchenberger (minors) | | | | | | | | | | | | | 4Yr | St. John's University (Queens, NY) |
| 1966 | 24 | | 469 | FrRnd | 9 | Phillies | Richard Seminoff (minors) | | | | | | | | | | | | | 4Yr | University of Arizona (Tucson, AZ) |
| 1966 | 24 | | 472 | FrRnd | 12 | Indians | Larry Edwards (minors) | | | | | | | | | | | | | 4Yr | Erskine College (Due West, SC) |
| 1966 | 24 | | 477 | FrRnd | 17 | Giants | Michael Babler (minors) | | | | | | | | | | | | | HS | St. Elizabeth HS (Oakland, CA) |
| 1966 | 24 | | 480 | FrRnd | 20 | Twins | Michael Colin (minors) | | | | | | | | | | | | | 4Yr | University of Washington (Seattle, WA) |
| 1966 | 25 | | 482 | FrRnd | 2 | Athletics | Rex Hein (minors) | | | | | | | | | | | | | HS | Rockhurst HS (Kansas City, MO) |
| 1966 | 25 | | 485 | FrRnd | 5 | Cubs | Dave Kent (minors) | | | | | | | | | | | | | HS | Hillsborough HS (Tampa, FL) |
| 1966 | 25 | | 486 | FrRnd | 6 | Senators | Gerry Schoen (minors) | -0.1 | 1 | 1 | 0 | .000 | .000 | 1 | 0 | 1 | 7.36 | 1.91 | 0 | 4Yr | Loyola University New Orleans (New Orleans, LA) |
| 1966 | 25 | | 488 | FrRnd | 8 | Angels | Clarence Smith (minors) | | | | | | | | | | | | | 4Yr | St. Francis University (Brooklyn, NY) |
| 1966 | 25 | | 489 | FrRnd | 9 | Phillies | Ben Farrell (minors) | | | | | | | | | | | | | 4Yr | Lipscomb University (Nashville, TN) |
| 1966 | 25 | | 490 | FrRnd | 10 | Yankees | Robert Dearrah (minors) | | | | | | | | | | | | | 4Yr | Tulane University (New Orleans, LA) |
| 1966 | 25 | | 498 | FrRnd | 18 | White Sox | Jim Limke (minors) | | | | | | | | | | | | | 4Yr | Minot State University (Minot, ND) |
| 1966 | 25 | | 500 | FrRnd | 20 | Twins | Robert Ziegler (minors) | | | | | | | | | | | | | 4Yr | Iowa State University (Ames, IA) |
| 1966 | 26 | | 506 | FrRnd | 6 | Senators | Gerry Pirtle (minors) | -1.5 | 19 | 0 | 0 | | | 19 | 0 | 2 | 5.96 | 2.18 | 0 | HS | Hale HS (Tulsa, OK) |
| 1966 | 26 | | 507 | FrRnd | 7 | Cardinals | Jim Panther (minors) | -2.4 | 85 | 9 | 0 | .111 | .311 | 85 | 7 | 13 | 5.26 | 1.66 | 0 | 4Yr | Southern Illinois University Carbondale (Carbondale, IL) |
| 1966 | 26 | | 511 | FrRnd | 11 | Braves | Ray Allen (minors) | | | | | | | | | | | | | JC | El Camino College (Torrance, CA) |
| 1966 | 26 | | 514 | FrRnd | 14 | Tigers | Nathanael Dixon (minors) | | | | | | | | | | | | | HS | Tuskegee HS (Tuskegee, AL) |
| 1966 | 26 | | 517 | FrRnd | 17 | Giants | Michael Wysocki (minors) | | | | | | | | | | | | | 4Yr | University of Georgia (Athens, GA) |
| 1966 | 26 | | 518 | FrRnd | 18 | White Sox | John Zotz (minors) | | | | | | | | | | | | | HS | Danville HS (Danville, IL) |
| 1966 | 26 | | 520 | FrRnd | 20 | Twins | Larry Walters (minors) | | | | | | | | | | | | | HS | Santiago HS (Garden Grove, CA) |
| 1966 | 27 | | 526 | FrRnd | 6 | Senators | Walter Collins (minors) | | | | | | | | | | | | | HS | Norview HS (Norfolk, VA) |
| 1966 | 27 | | 528 | FrRnd | 8 | Angels | Rick Well (minors) | | | | | | | | | | | | | HS | Bakersfield HS (Bakersfield, CA) |
| 1966 | 27 | | 532 | FrRnd | 12 | Reds | Conrad DeNeault (minors) | | | | | | | | | | | | | 4Yr | University of Missouri Columbia (Columbia, MO) |
| 1966 | 27 | | 534 | FrRnd | 14 | Pirates | Paul Mann (minors) | | | | | | | | | | | | | HS | Afton HS (St. Louis, MO) |
| 1966 | 27 | | 535 | FrRnd | 15 | Orioles | Richard Pecore (minors) | | | | | | | | | | | | | HS | St. Joseph's HS (Baltimore, MD) |
| 1966 | 27 | | 536 | FrRnd | 16 | Giants | Don Kirkland (minors) | | | | | | | | | | | | | 4Yr | Southern Illinois University Carbondale (Carbondale, IL) |
| 1966 | 27 | | 538 | FrRnd | 18 | Dodgers | Lawrence Land (minors) | | | | | | | | | | | | | HS | Bamberg HS (Bamberg, SC) |
| 1966 | 28 | | 541 | FrRnd | 2 | Athletics | Norbert Beddow (minors) | | | | | | | | | | | | | HS | Aurora HS (Aurora, CO) |
| 1966 | 28 | | 545 | FrRnd | 6 | Senators | Richard Bucholtz (minors) | | | | | | | | | | | | | HS | Burlington HS (Burlington, WI) |
| 1966 | 28 | | 555 | FrRnd | 16 | White Sox | James Daun (minors) | | | | | | | | | | | | | HS | Chilton HS (Chilton, WI) |
| 1966 | 29 | | 560 | FrRnd | 3 | Astros | Edmund Mantie (minors) | | | | | | | | | | | | | 4Yr | Syracuse University (Syracuse, NY) |
| 1966 | 29 | | 561 | FrRnd | 4 | Cubs | William Grogan (minors) | | | | | | | | | | | | | HS | Clarkston HS (Clarkston, WA) |
| 1966 | 29 | | 569 | FrRnd | 12 | Pirates | Gerry McCabe (minors) | | | | | | | | | | | | | HS | Cripple Creek-Victor HS (Victor, CO) |
| 1966 | 29 | | 570 | FrRnd | 13 | Orioles | Frank Bon Vardo (minors) | | | | | | | | | | | | | 4Yr | University of Maryland (College Park, MD) |
| 1966 | 29 | | 571 | FrRnd | 14 | Giants | Roy Johnson (minors) | | | | | | | | | | | | | HS | Canoga Park HS (Canoga Park, CA) |
| 1966 | 30 | | 575 | FrRnd | 1 | Mets | Richard Adams (minors) | | | | | | | | | | | | | HS | Chesterfield HS (Chesterfield, SC) |
| 1966 | 30 | | 578 | FrRnd | 4 | Cubs | Maurice Hartigan (minors) | | | | | | | | | | | | | JC | Columbia Basin College (Pasco, WA) |
| 1966 | 30 | | 582 | FrRnd | 8 | Yankees | Tim Marks (minors) | | | | | | | | | | | | | HS | Manual HS (Peoria, IL) |
| 1966 | 30 | | 583 | FrRnd | 9 | Braves | Kenneth Perrin (minors) | | | | | | | | | | | | | 4Yr | Texas A&M University (College Station, TX) |
| 1966 | 30 | | 585 | FrRnd | 11 | Tigers | Ron Timko (minors) | | | | | | | | | | | | | HS | Plains HS (Plains, PA) |
| 1966 | 30 | | 588 | FrRnd | 14 | Giants | Thomas Burgess (minors) | | | | | | | | | | | | | JC | Phoenix College (Phoenix, AZ) |
| 1966 | 30 | | 591 | FrRnd | 17 | Twins | Robert Bentley (minors) | | | | | | | | | | | | | 4Yr | University of Notre Dame (South Bend, IN) |
| 1966 | 31 | | 592 | FrRnd | 1 | Mets | Willie Richardson (minors) | | | | | | | | | | | | | HS | Burnet HS (Burnet, TX) |
| 1966 | 31 | | 595 | FrRnd | 4 | Cubs | Bill Stoneman (minors) | 4.5 | 253 | 338 | 0 | .086 | .246 | 245 | 54 | 85 | 4.08 | 1.44 | 5 | 4Yr | University of Idaho (Moscow, ID) |
| 1966 | 31 | | 596 | FrRnd | 5 | Senators | Bruce Baudier (minors) | | | | | | | | | | | | | 4Yr | Louisiana State University (Baton Rouge, LA) |
| 1966 | 31 | | 598 | FrRnd | 7 | Angels | Bill Bonham (minors) | 18.6 | 307 | 471 | 0 | .172 | .404 | 300 | 75 | 83 | 4.01 | 1.44 | 11 | HS | Francis Poly HS (Pacoima, CA) |
| 1966 | 31 | | 603 | FrRnd | 12 | Pirates | James Engel (minors) | | | | | | | | | | | | | | |
| 1966 | 32 | | 611 | FrRnd | 3 | Astros | Steven Evans (minors) | | | | | | | | | | | | | HS | Northville HS (Northville, MI) |
| 1966 | 32 | | 622 | FrRnd | 14 | Giants | Jerry Anding (minors) | | | | | | | | | | | | | 4Yr | California State University Northridge (Los Angeles, CA) |
| 1966 | 32 | | 623 | FrRnd | 15 | White Sox | David Smith (minors) | | | | | | | | | | | | | HS | Schaghticoke HS (Schaghticoke, NY) |
| 1966 | 32 | | 625 | FrRnd | 17 | Twins | Bob Castiglione (minors) | | | | | | | | | | | | | 4Yr | New York University (New York, NY) |
| 1966 | 33 | | 634 | FrRnd | 9 | Braves | Gary Ross (minors) | 2.9 | 283 | 61 | 0 | .115 | .260 | 283 | 25 | 47 | 3.92 | 1.47 | 7 | HS | Liberty-Portvue HS (Portvue, PA) |
| 1966 | 33 | | 635 | FrRnd | 10 | Indians | Dale Dunham (minors) | | | | | | | | | | | | | HS | Central HS (Bay City, MI) |
| 1966 | 33 | | 637 | FrRnd | 12 | Pirates | Michael Horn (minors) | | | | | | | | | | | | | HS | Boone County HS (Florence, KY) |
| 1966 | 33 | | 638 | FrRnd | 13 | Orioles | Richard Stevenson (minors) | | | | | | | | | | | | | HS | Parkville HS (Springfield, MD) |
| 1966 | 33 | | 639 | FrRnd | 14 | Giants | Phillip Thomas (minors) | | | | | | | | | | | | | HS | Tonganoxie HS (Tonganoxie, KS) |
| 1966 | 33 | | 640 | FrRnd | 15 | White Sox | John Davasko (minors) | | | | | | | | | | | | | 4Yr | St. Louis University (St. Louis, MO) |
| 1966 | 33 | | 641 | FrRnd | 16 | Dodgers | Ronald Reece (minors) | | | | | | | | | | | | | HS | Campbell HS (Smyrna, GA) |
| 1966 | 34 | | 644 | FrRnd | 2 | Athletics | Harold Werntz (minors) | | | | | | | | | | | | | 4Yr | Temple University (Philadelphia, PA) |
| 1966 | 34 | | 645 | FrRnd | 3 | Astros | Jeffrey Bowman (minors) | | | | | | | | | | | | | HS | Downey HS (Modesto, CA) |
| 1966 | 34 | | 648 | FrRnd | 6 | Cardinals | Frederick Covey (minors) | | | | | | | | | | | | | HS | Phillipsburg HS (Phillipsburg, NJ) |
| 1966 | 34 | | 651 | FrRnd | 9 | Braves | Brian Bach (minors) | | | | | | | | | | | | | HS | Kingston HS (Kingston, NY) |
| 1966 | 34 | | 652 | FrRnd | 10 | Indians | Dick Hall (minors) | | | | | | | | | | | | | HS | Memphis Catholic HS (Memphis, TN) |
| 1966 | 34 | | 654 | FrRnd | 12 | Pirates | Richard Jaggars (minors) | | | | | | | | | | | | | 4Yr | Gonzaga University (Spokane, WA) |
| 1966 | 34 | | 656 | FrRnd | 14 | Giants | Ray Strable (minors) | | | | | | | | | | | | | JC | College of the Sequoias (Visalia, CA) |
| 1966 | 35 | | 661 | FrRnd | 2 | Athletics | Charles Lynch (minors) | | | | | | | | | | | | | HS | Sayreville HS (Sayreville, NJ) |
| 1966 | 35 | | 663 | FrRnd | 4 | Cubs | Jim Nealey (minors) | | | | | | | | | | | | | HS | Corona HS (Corona, CA) |
| 1966 | 35 | | 668 | FrRnd | 9 | Tigers | Frank Sullivan (minors) | | | | | | | | | | | | | HS | Piscataway HS (Piscataway, NJ) |
| 1966 | 35 | | 669 | FrRnd | 10 | Pirates | James Skovron (minors) | | | | | | | | | | | | | HS | Pentucket Regional HS (West Newbury, MA) |
| 1966 | 36 | | 676 | FrRnd | 2 | Athletics | Tom Binder (minors) | | | | | | | | | | | | | HS | Ganesha HS (Pomona, CA) |
| 1966 | 36 | | 684 | FrRnd | 10 | Orioles | Robert Guerrera (minors) | | | | | | | | | | | | | HS | Crosby HS (Waterbury, CT) |
| 1966 | 36 | | 687 | FrRnd | 13 | Dodgers | Mark Harris (minors) | | | | | | | | | | | | | 4Yr | University of Maryland (College Park, MD) |
| 1966 | 36 | | 688 | FrRnd | 14 | Twins | Phillip Johnson (minors) | | | | | | | | | | | | | 4Yr | University of Northern Iowa (Cedar Falls, IA) |
| 1966 | 37 | | 690 | FrRnd | 2 | Astros | Mark Scally (minors) | | | | | | | | | | | | | HS | Archbishop Curley-Notre Dame HS (Miami, FL) |
| 1966 | 37 | | 695 | FrRnd | 7 | Pirates | Joseph Johnson (minors) | | | | | | | | | | | | | HS | Loyalsock HS (Williamsport, PA) |
| 1966 | 38 | | 701 | FrRnd | 1 | Mets | John Smith (minors) | | | | | | | | | | | | | HS | Irondequoit HS (Rochester, NY) |
| 1966 | 38 | | 703 | FrRnd | 3 | Cubs | Archie Reynolds (minors) | -1.5 | 36 | 11 | 0 | .273 | .792 | 36 | 0 | 8 | 5.73 | 1.82 | 0 | JC | Paris Junior College (Paris, TX) |
| 1966 | 38 | | 707 | FrRnd | 7 | Pirates | Rich Hand (minors) | 3.9 | 105 | 109 | 0 | .147 | .365 | 104 | 24 | 39 | 4.01 | 1.44 | 3 | HS | Lincoln HS (Seattle, WA) |
| 1966 | 38 | | 709 | FrRnd | 9 | Giants | Richard Wanless (minors) | | | | | | | | | | | | | HS | Quincy HS (Quincy, MA) |
| 1966 | 39 | | 718 | FrRnd | 6 | Pirates | Ronald Epperson (minors) | | | | | | | | | | | | | HS | Hudson's Bay HS (Vancouver, WA) |
| 1966 | 39 | | 721 | FrRnd | 9 | White Sox | Lawrance Hammer (minors) | | | | | | | | | | | | | HS | Fenger HS (Chicago, IL) |
| 1966 | 40 | | 726 | FrRnd | 3 | Yankees | James Price (minors) | | | | | | | | | | | | | HS | Skyline HS (Salt Lake City, UT) |
| 1966 | 40 | | 729 | FrRnd | 6 | Orioles | Billy Ferguson (minors) | | | | | | | | | | | | | HS | Holy Cross HS (Chalmette, LA) |
| 1966 | 40 | | 731 | FrRnd | 8 | White Sox | Edmund Curran (minors) | | | | | | | | | | | | | 4Yr | St. Louis University (St. Louis, MO) |
| 1966 | 40 | | 732 | FrRnd | 9 | Dodgers | Ray Lamb (minors) | 4.1 | 154 | 69 | 0 | .058 | .203 | 154 | 20 | 23 | 3.54 | 1.39 | 4 | 4Yr | University of Southern California (Los Angeles, CA) |
| 1966 | 41 | | 734 | FrRnd | 1 | Mets | Joseph Stover (minors) | | | | | | | | | | | | | 4Yr | William Carey College (Hattiesburg, MS) |
| 1966 | 41 | | 735 | FrRnd | 2 | Cardinals | Bruce MacLean (minors) | | | | | | | | | | | | | 4Yr | Bowdoin College (Brunswick, ME) |
| 1966 | 41 | | 740 | FrRnd | 7 | White Sox | Ken Kozil (minors) | | | | | | | | | | | | | HS | Glenbrook North HS (Northbrook, IL) |
| 1966 | 41 | | 741 | FrRnd | 8 | Dodgers | Donald Spain (minors) | | | | | | | | | | | | | HS | Eisenhower HS (Decatur, IL) |
| 1966 | 42 | | 744 | FrRnd | 2 | Cardinals | Buddy Smith (minors) | | | | | | | | | | | | | JC | Chipola College (Marianna, FL) |
| 1966 | 42 | | 745 | FrRnd | 3 | Yankees | David Steen (minors) | | | | | | | | | | | | | | |
| 1966 | 42 | | 748 | FrRnd | 6 | Dodgers | Donny Tidwell (minors) | | | | | | | | | | | | | HS | New Diana HS (New Diana, TX) |
| 1966 | 42 | | 749 | FrRnd | 7 | Twins | Henry Dennis (minors) | | | | | | | | | | | | | HS | Chatham HS (Chatham, NY) |
| 1966 | 43 | | 750 | FrRnd | 1 | Mets | Jim Zerilla (minors) | | | | | | | | | | | | | 4Yr | Parsons College (Fairfield, IA) |
| 1966 | 43 | | 754 | FrRnd | 5 | Orioles | Vaughn Kovach (minors) | | | | | | | | | | | | | 4Yr | West Virginia University (Morgantown, WV) |
| 1966 | 43 | | 756 | FrRnd | 7 | Twins | Robert Vaughn (minors) | | | | | | | | | | | | | JC | Cerritos College (Norwalk, CA) |
| 1966 | 44 | | 763 | FrRnd | 7 | Twins | Richard Erisman (minors) | | | | | | | | | | | | | HS | Lenape HS (Medford, NJ) |
| 1966 | 45 | | 766 | FrRnd | 3 | Yankees | Jim Pope (minors) | | | | | | | | | | | | | HS | Pasco HS (Pasco, WA) |
| 1966 | 46 | | 771 | FrRnd | 1 | Mets | Stephen Brasher (minors) | | | | | | | | | | | | | 4Yr | University of Arizona (Tucson, AZ) |
| 1966 | 46 | | 772 | FrRnd | 2 | Cardinals | Larry Azevedo (minors) | | | | | | | | | | | | | HS | Hilman HS (Hilman, CA) |
| 1966 | 46 | | 776 | FrRnd | 6 | Dodgers | Jeffrey King (minors) | | | | | | | | | | | | | HS | Mainland HS (Daytona Beach, FL) |
| 1966 | 47 | | 778 | FrRnd | 1 | Mets | Robert Haines (minors) | | | | | | | | | | | | | JC | Columbia Basin College (Pasco, WA) |
| 1966 | 47 | | 783 | FrRnd | 6 | Twins | Thomas Staach (minors) | | | | | | | | | | | | | 4Yr | University of Iowa (Iowa City, IA) |
| 1966 | 48 | | 784 | FrRnd | 1 | Mets | Billy Haynes (minors) | | | | | | | | | | | | | HS | East Rowan HS (Salisbury, NC) |
| 1966 | 49 | | 791 | FrRnd | 2 | Yankees | William Shepherd (minors) | | | | | | | | | | | | | HS | John R Rogers HS (Spokane, WA) |
| 1966 | 49 | | 794 | FrRnd | 5 | Dodgers | Jody Gioffoni (minors) | | | | | | | | | | | | | HS | Santa Monica HS (Santa Monica, CA) |
| 1966 | 50 | | 797 | FrRnd | 2 | Yankees | Al Simmons (minors) | | | | | | | | | | | | | 4Yr | University of Idaho (Moscow, ID) |
| 1966 | 51 | | 800 | FrRnd | 1 | Mets | John Hilts (minors) | | | | | | | | | | | | | 4Yr | University of Wyoming (Laramie, WY) |
| 1966 | 51 | | 802 | FrRnd | 3 | Braves | William Matusz (minors) | | | | | | | | | | | | | 4Yr | Seton Hall University (South Orange, NJ) |
| 1966 | 53 | | 809 | FrRnd | 2 | Braves | Larry Brown (minors) | | | | | | | | | | | | | HS | Wichita HS (Wichita, KS) |
| 1966 | 53 | | 810 | FrRnd | 3 | Dodgers | Jack Butorac (minors) | | | | | | | | | | | | | HS | Montebello HS (Montebello, CA) |
| 1966 | 55 | | 814 | FrRnd | 1 | Yankees | Gilbert Scharringhausen (minors) | | | | | | | | | | | | | 4Yr | Portland State University (Portland, OR) |
| 1966 | 55 | | 815 | FrRnd | 2 | Braves | James Conklin (minors) | | | | | | | | | | | | | HS | Tuxedo HS (Tuxedo, NY) |
| 1966 | 56 | | 819 | FrRnd | 3 | Dodgers | Francis Staab (minors) | | | | | | | | | | | | | HS | Hays HS (Hays, KS) |
| 1966 | 58 | | 824 | FrRnd | 2 | Dodgers | Adrian Zabala (minors) | | | | | | | | | | | | | 4Yr | University of Florida (Gainesville, FL) |
| 1966 | 59 | | 825 | FrRnd | 1 | Yankees | Walter Prior (minors) | | | | | | | | | | | | | 4Yr | University of Florida (Gainesville, FL) |
| 1966 | 60 | | 828 | FrRnd | 2 | Dodgers | Tom Smith (minors) | | | | | | | | | | | | | HS | Foley HS (Foley, AL) |
| 1966 | 61 | | 830 | FrRnd | 2 | Dodgers | James Raynor (minors) | | | | | | | | | | | | | HS | Hamilton HS (Robbinsville, NJ) |
| 1966 | 62 | | 831 | FrRnd | 1 | Yankees | Frank Brennan (minors) | | | | | | | | | | | | | 4Yr | Fairleigh Dickinson University, Metropolitan Campus (Teaneck, NJ) |